• dr Kinga Ślósarczyk
Position: starszy technik
Unit: Wydział Nauk Przyrodniczych
Adress: 41-200 Sosnowiec, ul. Będzińska 60
Floor: V
Room: 517
Phone: (32) 3689 314
E-mail: kinga.slosarczyk@us.edu.pl
Publications list: Publications by CINiBA
Publications list: Publications by OPUS
Scopus Author ID: 57204353544
Publications from the Scopus database
2022
Jakóbczyk-Karpierz, S.; Ślósarczyk, K.
In: Journal of Hydrology, vol. 612, 2022, ISSN: 00221694, (2).
@article{2-s2.0-85135370062,
title = {Isotopic signature of anthropogenic sources of groundwater contamination with sulfate and its application to groundwater in a heavily urbanized and industrialized area (Upper Silesia, Poland)},
author = { S. Jakóbczyk-Karpierz and K. Ślósarczyk},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85135370062&doi=10.1016%2fj.jhydrol.2022.128255&partnerID=40&md5=d7dd1ef67efd7760e5cb205a2b7a4bd0},
doi = {10.1016/j.jhydrol.2022.128255},
issn = {00221694},
year = {2022},
date = {2022-01-01},
journal = {Journal of Hydrology},
volume = {612},
publisher = {Elsevier B.V.},
abstract = {Isotopic signatures of anthropogenic sulfate sources within the Upper Silesian urban area (southern Poland) were investigated to increase the reliability of the origin assessment of groundwater contaminants. To analyze δ34S and δ18O in sulfate, 64 samples were collected, representing several sulfate sources: synthetic and organic fertilizers, raw and treated wastewater, mine water, leachate from landfills, mine heaps, and industrial waste dumps. Additionally, 10 surface water samples were taken from contaminated rivers regarded as potential groundwater pollution sources. Results of δ34S and δ18O in sulfate derived from anthropogenic sources were compared with literature data, which indicated significant discrepancies for some contamination sources. The results were applied to assess SO42- origin in groundwater samples from the Gliwice aquifer. Apart from the δ34S and δ18O data, the study included measurements of major ions, inorganic nitrogen forms, trichloroethene and tetrachloroethene in groundwater. Isotopic analyses of river water samples confirmed the impact of urbanized and industrialized areas on surface water pollution and possible influence on groundwater contamination. The values of δ34S and δ18O similar to wastewater were reported for most groundwater samples from the Gliwice carbonate aquifer. Groundwater contamination was also manifested by higher values of electrical conductivity and concentrations of chloride, sodium, trichloroethene and tetrachloroethene. The comparison of recent isotopic data on SO42- sources with literature values clearly shows that it is very important to investigate local potential contamination sources to increase their reliability in determining the source of groundwater or river water pollution. © 2022 The Author(s)},
note = {2},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Isotopic signatures of anthropogenic sulfate sources within the Upper Silesian urban area (southern Poland) were investigated to increase the reliability of the origin assessment of groundwater contaminants. To analyze δ34S and δ18O in sulfate, 64 samples were collected, representing several sulfate sources: synthetic and organic fertilizers, raw and treated wastewater, mine water, leachate from landfills, mine heaps, and industrial waste dumps. Additionally, 10 surface water samples were taken from contaminated rivers regarded as potential groundwater pollution sources. Results of δ34S and δ18O in sulfate derived from anthropogenic sources were compared with literature data, which indicated significant discrepancies for some contamination sources. The results were applied to assess SO42- origin in groundwater samples from the Gliwice aquifer. Apart from the δ34S and δ18O data, the study included measurements of major ions, inorganic nitrogen forms, trichloroethene and tetrachloroethene in groundwater. Isotopic analyses of river water samples confirmed the impact of urbanized and industrialized areas on surface water pollution and possible influence on groundwater contamination. The values of δ34S and δ18O similar to wastewater were reported for most groundwater samples from the Gliwice carbonate aquifer. Groundwater contamination was also manifested by higher values of electrical conductivity and concentrations of chloride, sodium, trichloroethene and tetrachloroethene. The comparison of recent isotopic data on SO42- sources with literature values clearly shows that it is very important to investigate local potential contamination sources to increase their reliability in determining the source of groundwater or river water pollution. © 2022 The Author(s)
Ślósarczyk, K.; Jakóbczyk-Karpierz, S.; Witkowski, A. J.
In: Water (Switzerland), vol. 14, no. 6, 2022, ISSN: 20734441, (1).
@article{2-s2.0-85126358541,
title = {Identification of Water Contamination Sources Using Hydrochemical and Isotopic Studies—The Kozłowa Góra Reservoir Catchment Area (Southern Poland)},
author = { K. Ślósarczyk and S. Jakóbczyk-Karpierz and A.J. Witkowski},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85126358541&doi=10.3390%2fw14060846&partnerID=40&md5=e498a1a5d4ebf0e3031382e0676baf5d},
doi = {10.3390/w14060846},
issn = {20734441},
year = {2022},
date = {2022-01-01},
journal = {Water (Switzerland)},
volume = {14},
number = {6},
publisher = {MDPI},
abstract = {The application of combined research methods, such as hydrochemical and isotopic anal-yses, facilitates understanding of the origin of water constituents and migration of contaminants in the aquatic environment. The presented study attempts to identify contamination sources affecting water quality within the Kozłowa Góra reservoir catchment area (southern Poland). A total of 100 water samples were collected from surface water (the Brynica river; streams; and the reservoir) and groundwater (a Quarternary aquifer) in four time periods. During fieldwork, the physicochemical parameters were measured (temperature; pH; electrical conductivity; redox potential; and dissolved oxygen). The chemical analysis included the determination of major ions (HCO3−; SO42−; Cl−; Ca2+; Mg2+; Na+; and K+), nutrients (NO3−; NO2−; NH4+; and PO43−), and total organic carbon. The study was complemented by isotopic analysis of sulphur and oxygen in sulphate, which enabled a more pre-cise identification of stressors affecting water quality in different parts of the catchment area. Chemical and isotopic results (δ34S = 4.38–13.99‰; δ18O 3.59–13.30‰) revealed that wastewater discharges and agricultural activities have a significant influence on the chemistry of the Brynica River and other streams. At some sampling points, a lower quality of water was manifested by elevated concentrations of NO3− (up to 22.6 mg/L) and several other ions (e.g.; up to 114 mg/L for Cl−; up to 51.52 mg/L for NH4+; and 12.5 mg/L for PO43−). The quality of groundwater was deteriorated mainly by infiltration of sewage from leaky septic tanks. The level of groundwater contamination varied depending on the location, as higher concentrations of major ions and values of electrical conductivity were observed in residential areas. The Brynica river, streams, and groundwater recharge the drinking water reservoir, and thus its quality depends on these sources. A dilution of water and the presence of biochemical processes led to a reduction of contaminant concentrations in the Kozłowa Góra reservoir (down to 3.5 mg/L for NO3−; 32 mg/L for Cl−; 0.21 mg/L for NH4+; and <0.05 mg/L for PO43−) compared to water in the river and streams supplying the reservoir. The study revealed the role of wastewater discharge and agricultural activities in the evolution of surface water chemistry. The results will be used in further research on the origin and migration of other substances in water, including microcontaminants. © 2022 by the authors. Licensee MDPI, Basel, Switzerland.},
note = {1},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
The application of combined research methods, such as hydrochemical and isotopic anal-yses, facilitates understanding of the origin of water constituents and migration of contaminants in the aquatic environment. The presented study attempts to identify contamination sources affecting water quality within the Kozłowa Góra reservoir catchment area (southern Poland). A total of 100 water samples were collected from surface water (the Brynica river; streams; and the reservoir) and groundwater (a Quarternary aquifer) in four time periods. During fieldwork, the physicochemical parameters were measured (temperature; pH; electrical conductivity; redox potential; and dissolved oxygen). The chemical analysis included the determination of major ions (HCO3−; SO42−; Cl−; Ca2+; Mg2+; Na+; and K+), nutrients (NO3−; NO2−; NH4+; and PO43−), and total organic carbon. The study was complemented by isotopic analysis of sulphur and oxygen in sulphate, which enabled a more pre-cise identification of stressors affecting water quality in different parts of the catchment area. Chemical and isotopic results (δ34S = 4.38–13.99‰; δ18O 3.59–13.30‰) revealed that wastewater discharges and agricultural activities have a significant influence on the chemistry of the Brynica River and other streams. At some sampling points, a lower quality of water was manifested by elevated concentrations of NO3− (up to 22.6 mg/L) and several other ions (e.g.; up to 114 mg/L for Cl−; up to 51.52 mg/L for NH4+; and 12.5 mg/L for PO43−). The quality of groundwater was deteriorated mainly by infiltration of sewage from leaky septic tanks. The level of groundwater contamination varied depending on the location, as higher concentrations of major ions and values of electrical conductivity were observed in residential areas. The Brynica river, streams, and groundwater recharge the drinking water reservoir, and thus its quality depends on these sources. A dilution of water and the presence of biochemical processes led to a reduction of contaminant concentrations in the Kozłowa Góra reservoir (down to 3.5 mg/L for NO3−; 32 mg/L for Cl−; 0.21 mg/L for NH4+; and <0.05 mg/L for PO43−) compared to water in the river and streams supplying the reservoir. The study revealed the role of wastewater discharge and agricultural activities in the evolution of surface water chemistry. The results will be used in further research on the origin and migration of other substances in water, including microcontaminants. © 2022 by the authors. Licensee MDPI, Basel, Switzerland.
2021
Ślósarczyk, K.; Witkowski, A. J.
Preliminary evaluation of the possible occurrence of pesticides in groundwater contaminated with nitrates—a case study from southern poland Journal Article
In: Water (Switzerland), vol. 13, no. 21, 2021, ISSN: 20734441, (3).
@article{2-s2.0-85118763965,
title = {Preliminary evaluation of the possible occurrence of pesticides in groundwater contaminated with nitrates—a case study from southern poland},
author = { K. Ślósarczyk and A.J. Witkowski},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85118763965&doi=10.3390%2fw13213091&partnerID=40&md5=f735baaea10fe0a139d014769fe00770},
doi = {10.3390/w13213091},
issn = {20734441},
year = {2021},
date = {2021-01-01},
journal = {Water (Switzerland)},
volume = {13},
number = {21},
publisher = {MDPI},
abstract = {This paper addresses groundwater pollution and the potential presence of pesticides within the catchment areas of two reservoirs that are sources of drinking water. The two reservoirs are Goczałkowice and Kozłowa Góra, both in Southern Poland. Agricultural and rural areas dominate both catchments. Archival data showed local groundwater contamination with nitrates. This indicated the possible presence of pesticides in shallow groundwater. In total, 13 groundwater samples from shallow sandy aquifers were collected. All the samples were tested for the presence of 35 organophosphate pesticides and 28 organochlorine pesticides. Additionally, in order to determine the current groundwater conditions, physicochemical parameters were measured in the field, and water samples were subjected to analysis of their chemical composition (incl. the determination of nitrates). The research outcomes showed that pesticides were not detected above the detection limits in any of the samples. Due to variations in the persistence and degradation rates of pesticides, the occurrence of these substances in the groundwater environment and the possibility of their migration to aquifers should not be completely excluded. Natural processes and factors (e.g.; sorption; biodegradation; hydrolysis and redox conditions) may gradually reduce the pesticide concentrations in groundwater. The chemical analyses revealed high concentrations of nitrates in the groundwater. This suggests the possible influence of agriculture and fertilizer application on groundwater quality; however, a proportion of NO3- ions may be connected with improper sewage management within the two catchments. The absence of pesticides in groundwater impacted by agriculture may result from processes occurring in the aquifer and the rapid degradation of these compounds due to photolysis and prevailing weather conditions. In the vicinity of dwellings, nitrates also originate from domestic wastewater. Thus, the occurrence of pesticides in groundwater contaminated with NO3 cannot always be expected. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.},
note = {3},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
This paper addresses groundwater pollution and the potential presence of pesticides within the catchment areas of two reservoirs that are sources of drinking water. The two reservoirs are Goczałkowice and Kozłowa Góra, both in Southern Poland. Agricultural and rural areas dominate both catchments. Archival data showed local groundwater contamination with nitrates. This indicated the possible presence of pesticides in shallow groundwater. In total, 13 groundwater samples from shallow sandy aquifers were collected. All the samples were tested for the presence of 35 organophosphate pesticides and 28 organochlorine pesticides. Additionally, in order to determine the current groundwater conditions, physicochemical parameters were measured in the field, and water samples were subjected to analysis of their chemical composition (incl. the determination of nitrates). The research outcomes showed that pesticides were not detected above the detection limits in any of the samples. Due to variations in the persistence and degradation rates of pesticides, the occurrence of these substances in the groundwater environment and the possibility of their migration to aquifers should not be completely excluded. Natural processes and factors (e.g.; sorption; biodegradation; hydrolysis and redox conditions) may gradually reduce the pesticide concentrations in groundwater. The chemical analyses revealed high concentrations of nitrates in the groundwater. This suggests the possible influence of agriculture and fertilizer application on groundwater quality; however, a proportion of NO3- ions may be connected with improper sewage management within the two catchments. The absence of pesticides in groundwater impacted by agriculture may result from processes occurring in the aquifer and the rapid degradation of these compounds due to photolysis and prevailing weather conditions. In the vicinity of dwellings, nitrates also originate from domestic wastewater. Thus, the occurrence of pesticides in groundwater contaminated with NO3 cannot always be expected. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.
Ślósarczyk, K.; Jakóbczyk-Karpierz, S.; Różkowski, J.; Witkowski, A. J.
Occurrence of pharmaceuticals and personal care products in the water environment of Poland: A review Journal Article
In: Water (Switzerland), vol. 13, no. 16, 2021, ISSN: 20734441, (5).
@article{2-s2.0-85113770401,
title = {Occurrence of pharmaceuticals and personal care products in the water environment of Poland: A review},
author = { K. Ślósarczyk and S. Jakóbczyk-Karpierz and J. Różkowski and A.J. Witkowski},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85113770401&doi=10.3390%2fw13162283&partnerID=40&md5=dd9d80ae30e1ef5da6bad75f60157b94},
doi = {10.3390/w13162283},
issn = {20734441},
year = {2021},
date = {2021-01-01},
journal = {Water (Switzerland)},
volume = {13},
number = {16},
publisher = {MDPI AG},
abstract = {The issue of pharmaceuticals and personal care products (PPCPs) in the water environment has gained increasing interest worldwide. To determine the nature and extent of this problem for Poland, this paper presents a review of research on the presence of PPCPs in Poland, looking at results for different water samples, including wastewater (before and after treatment), landfill leachate, surface water (standing water bodies and rivers), seawater, groundwater and drinking water. The review is based on over 50 scientific articles and dissertations referring to studies of PPCPs. It also briefly outlines possible sources and the fate of PPCPs in the aquatic environment. The review of Polish research has revealed that studies have previously covered at least 39 PPCP groups (270 compounds in total). These studies focused mainly on wastewater and rivers, and only a few concerned landfill leachate and seawater. They most often reported on nonsteroidal anti-inflammatory drugs and antibiotics. The highest concentrations of the analysed PPCPs were found mainly in raw wastewater (e.g.; naproxen; up to 551;960 ng/L), but they were also occasionally found in surface water (e.g.; azithromycin; erythromycin; irbesartan and metoprolol) and in groundwater (e.g.; N;N-diethyl-meta-toluamide; known as DEET; up to 17;280 ng/L). Extremely high concentrations of bisphenol A (up to 2;202;000 ng/L) and diclofenac (up to 108;340 ng/L) were found in landfill leachate. Although numerous substances have been detected, PPCPs are still not monitored regularly, which makes it difficult to obtain a clear understanding of their incidence in the water environment. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.},
note = {5},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
The issue of pharmaceuticals and personal care products (PPCPs) in the water environment has gained increasing interest worldwide. To determine the nature and extent of this problem for Poland, this paper presents a review of research on the presence of PPCPs in Poland, looking at results for different water samples, including wastewater (before and after treatment), landfill leachate, surface water (standing water bodies and rivers), seawater, groundwater and drinking water. The review is based on over 50 scientific articles and dissertations referring to studies of PPCPs. It also briefly outlines possible sources and the fate of PPCPs in the aquatic environment. The review of Polish research has revealed that studies have previously covered at least 39 PPCP groups (270 compounds in total). These studies focused mainly on wastewater and rivers, and only a few concerned landfill leachate and seawater. They most often reported on nonsteroidal anti-inflammatory drugs and antibiotics. The highest concentrations of the analysed PPCPs were found mainly in raw wastewater (e.g.; naproxen; up to 551;960 ng/L), but they were also occasionally found in surface water (e.g.; azithromycin; erythromycin; irbesartan and metoprolol) and in groundwater (e.g.; N;N-diethyl-meta-toluamide; known as DEET; up to 17;280 ng/L). Extremely high concentrations of bisphenol A (up to 2;202;000 ng/L) and diclofenac (up to 108;340 ng/L) were found in landfill leachate. Although numerous substances have been detected, PPCPs are still not monitored regularly, which makes it difficult to obtain a clear understanding of their incidence in the water environment. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.
2020
Jakóbczyk-Karpierz, S.; Ślósarczyk, K.; Sitek, S. S.
In: Applied Geochemistry, vol. 118, 2020, ISSN: 08832927, (7).
@article{2-s2.0-85084362774,
title = {Tracing multiple sources of groundwater pollution in a complex carbonate aquifer (Tarnowskie Góry, southern Poland) using hydrogeochemical tracers, TCE, PCE, SF6 and CFCs},
author = { S. Jakóbczyk-Karpierz and K. Ślósarczyk and S.S. Sitek},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85084362774&doi=10.1016%2fj.apgeochem.2020.104623&partnerID=40&md5=4f7f9838d29344041202498c40263491},
doi = {10.1016/j.apgeochem.2020.104623},
issn = {08832927},
year = {2020},
date = {2020-01-01},
urldate = {2020-01-01},
journal = {Applied Geochemistry},
volume = {118},
publisher = {Elsevier Ltd},
abstract = {A comprehensive study on the sources of groundwater contamination in the Triassic carbonate aquifer, southern Poland, was conducted. The Gliwice aquifer is an important source of potable water in the Silesia region, the most industrialized part of Poland. Groundwater quality has been deteriorating over the last decades, which encouraged researchers to undertake comprehensive study to identify the sources and fates of the observed pollution. The presented study comprised analyses of major and minor ions, trichloroethylene (TCE) and tetrachloroethylene (PCE), CFC-11, CFC-12, SF6, Ne and Ar in groundwater. The results showed that shallow groundwater within the Tarnowskie Góry town, located in the recharge zone of the aquifer, was more contaminated than groundwater abstracted from deeper part of the aquifer within the town, as well as groundwater located downgradient. A contamination plume of boron indicated an impact of the closed chemical plant, operating in the 20th century. Groundwater in the vicinity of the chemical plant was significantly altered, which was manifested by elevated concentrations of Cl−, SO4 2-, Na+, total Fe and Mn. The study revealed groundwater contamination with CFC-11 and CFC-12. Comparison of concentrations obtained in two field campaigns (in 2010 and 2015) showed an increase in the extent of pollution plumes. The third analysed gaseous tracer, SF6, did not appear to come from non-atmospheric sources, therefore, it was possible to calculate groundwater age using lumped parameter models. The results showed relatively young ages of the analysed groundwater samples, from 4 to 5 to 30–50 years. The youngest groundwater were found close to the Drama River, suggesting infiltration of the surface water into the carbonate aquifer. This feature of the river was confirmed by the observation of TCE and PCE concentrations in groundwater. Central part of the Tarnowskie Góry town was a source area for TCE and PCE contamination. Two directions of pollutants migration were observed, one of them was induced by the drainage of the historic ore mine and subsequently the Drama River – recipient of water coming from the mine drainage. © 2020 Elsevier Ltd},
note = {7},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
A comprehensive study on the sources of groundwater contamination in the Triassic carbonate aquifer, southern Poland, was conducted. The Gliwice aquifer is an important source of potable water in the Silesia region, the most industrialized part of Poland. Groundwater quality has been deteriorating over the last decades, which encouraged researchers to undertake comprehensive study to identify the sources and fates of the observed pollution. The presented study comprised analyses of major and minor ions, trichloroethylene (TCE) and tetrachloroethylene (PCE), CFC-11, CFC-12, SF6, Ne and Ar in groundwater. The results showed that shallow groundwater within the Tarnowskie Góry town, located in the recharge zone of the aquifer, was more contaminated than groundwater abstracted from deeper part of the aquifer within the town, as well as groundwater located downgradient. A contamination plume of boron indicated an impact of the closed chemical plant, operating in the 20th century. Groundwater in the vicinity of the chemical plant was significantly altered, which was manifested by elevated concentrations of Cl−, SO4 2-, Na+, total Fe and Mn. The study revealed groundwater contamination with CFC-11 and CFC-12. Comparison of concentrations obtained in two field campaigns (in 2010 and 2015) showed an increase in the extent of pollution plumes. The third analysed gaseous tracer, SF6, did not appear to come from non-atmospheric sources, therefore, it was possible to calculate groundwater age using lumped parameter models. The results showed relatively young ages of the analysed groundwater samples, from 4 to 5 to 30–50 years. The youngest groundwater were found close to the Drama River, suggesting infiltration of the surface water into the carbonate aquifer. This feature of the river was confirmed by the observation of TCE and PCE concentrations in groundwater. Central part of the Tarnowskie Góry town was a source area for TCE and PCE contamination. Two directions of pollutants migration were observed, one of them was induced by the drainage of the historic ore mine and subsequently the Drama River – recipient of water coming from the mine drainage. © 2020 Elsevier Ltd
Witkowski, A. J.; Ślósarczyk, K.
Polish Geological Institute, vol. 68, no. 4, 2020, ISSN: 00332151.
@proceedings{2-s2.0-85096346893,
title = {Paradoxes in regulations on polycyelic aromatic hydrocarbons (PAH) in water [Paradoksy w unormowaniach prawnych dotyczących zawartości wielopierścieniowych wȩglowodorów aromatycznych (WWA) w wodach]},
author = { A.J. Witkowski and K. Ślósarczyk},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85096346893&doi=10.7306%2f2020.13&partnerID=40&md5=4245716dd15d63d751816d96afbe5852},
doi = {10.7306/2020.13},
issn = {00332151},
year = {2020},
date = {2020-01-01},
journal = {Przeglad Geologiczny},
volume = {68},
number = {4},
pages = {256-262},
publisher = {Polish Geological Institute},
abstract = {The paper provides an analysis of current Polish regulations on polycyelic aromatic hydrocarbons (PAH) in water. The issue was also described in relation to international law. Inconsistency in regulations in terms of definitions of the sum of PAH is highlighted. The influence of PAH concentrations on the classification of water chemical status and the assessment of drinking water quality was analyzed based on the results of concentrations of six PAHs: benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(a)pyrene, diben-zo(ah)anthracene, benzo(ghi)perylene and indeno(l;2;3-cd)pyrene. The PAH concentrations were determined in 36 water samples, including 28 samples of spring water and eight samples of snowmelt. The results obtained for most of the samples revealed elevated concentrations of benzo(a)pyrene. The authors underline the fact that a separate assessment ofbenzo(a)pyrene, the sum of six PAHs, and the sum of four PAHs unveil inconsistency in water quality evaluation. The results also suggest that only benzo(a)pyrene should be considered in the classifications mentioned, since its determination gives the actual view on the water quality in terms of PAH concentrations. The assessments for the sum of six PAHs and four PAHs in accordance with existing regulations indicate higher quality classes, meaning a better water quality in comparison with the concentration of benzo(a)pyrene itself. © 2020 Polish Geological Institute. All rights reserved.},
keywords = {},
pubstate = {published},
tppubtype = {proceedings}
}
The paper provides an analysis of current Polish regulations on polycyelic aromatic hydrocarbons (PAH) in water. The issue was also described in relation to international law. Inconsistency in regulations in terms of definitions of the sum of PAH is highlighted. The influence of PAH concentrations on the classification of water chemical status and the assessment of drinking water quality was analyzed based on the results of concentrations of six PAHs: benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(a)pyrene, diben-zo(ah)anthracene, benzo(ghi)perylene and indeno(l;2;3-cd)pyrene. The PAH concentrations were determined in 36 water samples, including 28 samples of spring water and eight samples of snowmelt. The results obtained for most of the samples revealed elevated concentrations of benzo(a)pyrene. The authors underline the fact that a separate assessment ofbenzo(a)pyrene, the sum of six PAHs, and the sum of four PAHs unveil inconsistency in water quality evaluation. The results also suggest that only benzo(a)pyrene should be considered in the classifications mentioned, since its determination gives the actual view on the water quality in terms of PAH concentrations. The assessments for the sum of six PAHs and four PAHs in accordance with existing regulations indicate higher quality classes, meaning a better water quality in comparison with the concentration of benzo(a)pyrene itself. © 2020 Polish Geological Institute. All rights reserved.
Różkowski, J.; Ślósarczyk, K.; Jakóbczyk-Karpierz, S.; Rubin, H.
Polish Geological Institute, vol. 68, no. 4, 2020, ISSN: 00332151, (1).
@proceedings{2-s2.0-85096340252,
title = {Occurrence, sources of PAHs, and groundwater protection against pollution in the Cieszyńskie ródła Tufowe Natura 2000 area [Wysţpowanie i geneza WWA w wodach podziemnych obszaru Natura 2000 Cieszyńskie ródła Tufowe oraz ochrona tych wód przed zanieczyszczeniem]},
author = { J. Różkowski and K. Ślósarczyk and S. Jakóbczyk-Karpierz and H. Rubin},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85096340252&doi=10.7306%2f2020.12&partnerID=40&md5=a390b2d497b474260b8fde3185ca31fb},
doi = {10.7306/2020.12},
issn = {00332151},
year = {2020},
date = {2020-01-01},
journal = {Przeglad Geologiczny},
volume = {68},
number = {4},
pages = {249-255},
publisher = {Polish Geological Institute},
abstract = {The paper deals with the problem of groundwater pollution with polycyclic aromatic hydrocarbons (PAHs) in the "Cieszyńskie ródła Tufowe " Natura 2000 area. The concentration of 16 PAHs was measured with the use of the GC-MS method in seven water samples collected from the area of four enclaves belonging to the nature reserve. The results of analyses were compared with both the hydrogeochemical background and the limit value of PAHs concentration in drinking water, defined in the Regulation of the Minister for Health. Additionally, in order to determine the origin of contamination, PAH ratios for selected compounds were calculated. The paper also highlights the importance of the PAHs monitoring in groundwater. © 2020 Polish Geological Institute. All rights reserved.},
note = {1},
keywords = {},
pubstate = {published},
tppubtype = {proceedings}
}
The paper deals with the problem of groundwater pollution with polycyclic aromatic hydrocarbons (PAHs) in the "Cieszyńskie ródła Tufowe " Natura 2000 area. The concentration of 16 PAHs was measured with the use of the GC-MS method in seven water samples collected from the area of four enclaves belonging to the nature reserve. The results of analyses were compared with both the hydrogeochemical background and the limit value of PAHs concentration in drinking water, defined in the Regulation of the Minister for Health. Additionally, in order to determine the origin of contamination, PAH ratios for selected compounds were calculated. The paper also highlights the importance of the PAHs monitoring in groundwater. © 2020 Polish Geological Institute. All rights reserved.
2019
Rubin, K.; Rubin, H.; Różkowski, J.; Ślósarczyk, K.; Flasza, A.
In: Biuletyn - Panstwowego Instytutu Geologicznego, vol. 475, no. 475, pp. 199-204, 2019, ISSN: 08676143.
@article{2-s2.0-85108084188,
title = {Risk assessment for the catchment zone of the łazy błȩdowskie GPW s.a. groundwater intake in katowice and its limitations [ANALIZA RYZYKA DLA OBSZARU SPłYWU WÓD PODZIEMNYCH DO UJȩCIA łaZY BłȩDOWSKIE GPW S.A. W KATOWICACH I JEJ OGRANICZENIA]},
author = { K. Rubin and H. Rubin and J. Różkowski and K. Ślósarczyk and A. Flasza},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85108084188&doi=10.7306%2fbpig.24&partnerID=40&md5=8e68c456701c4c799737630cd6ea80f2},
doi = {10.7306/bpig.24},
issn = {08676143},
year = {2019},
date = {2019-01-01},
journal = {Biuletyn - Panstwowego Instytutu Geologicznego},
volume = {475},
number = {475},
pages = {199-204},
publisher = {Polish Geological Institute},
abstract = {The paper presents the procedure of risk assessment for the catchment zone of the łazy Błȩdowskie groundwater intake, performed in accordance with the Water Law Act. Identification and analysis of contamination sources resulting from the land use patterns, as well as water qualitative research and health risk assessment with a view to factors negatively affecting the water quality, were carried out based on the hydrogeological report and analyses. The limitation on risk assessment, constrained by specific local hydrogeological, hydrogeochemical and environmental conditions, was indicated, including the need to establish the sanitary protection zone for the 8bis well. The planned cessation of the activities of Zn-Pb ores mining in the Olkusz area and associated changes in hydrogeochemical and hydrodynamic conditions within the area of the łazy Błȩdowskie groundwater intake were taken into account as well. © 2019 Polish Geological Institute. All rights reserved.},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
The paper presents the procedure of risk assessment for the catchment zone of the łazy Błȩdowskie groundwater intake, performed in accordance with the Water Law Act. Identification and analysis of contamination sources resulting from the land use patterns, as well as water qualitative research and health risk assessment with a view to factors negatively affecting the water quality, were carried out based on the hydrogeological report and analyses. The limitation on risk assessment, constrained by specific local hydrogeological, hydrogeochemical and environmental conditions, was indicated, including the need to establish the sanitary protection zone for the 8bis well. The planned cessation of the activities of Zn-Pb ores mining in the Olkusz area and associated changes in hydrogeochemical and hydrodynamic conditions within the area of the łazy Błȩdowskie groundwater intake were taken into account as well. © 2019 Polish Geological Institute. All rights reserved.
Jakóbczyk-Karpierz, S.; Ślósarczyk, K.
International Multidisciplinary Scientific Geoconference, vol. 19, no. 1.2, 2019, ISSN: 13142704.
@proceedings{2-s2.0-85073698937,
title = {Application of geochemical and isotopic study (δ15nno3, δ18ono3, δ34 sso4, δ18 oso4) to assess the extent of human impact on groundwater quality in the area of kuŹnica warĘŻyŃska reservoir (southern poland)},
author = { S. Jakóbczyk-Karpierz and K. Ślósarczyk},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85073698937&doi=10.5593%2fsgem2019%2f1.2%2fS02.010&partnerID=40&md5=f5320fc6bab350eeb98828a543ef4ae5},
doi = {10.5593/sgem2019/1.2/S02.010},
issn = {13142704},
year = {2019},
date = {2019-01-01},
journal = {International Multidisciplinary Scientific GeoConference Surveying Geology and Mining Ecology Management, SGEM},
volume = {19},
number = {1.2},
pages = {71-78},
publisher = {International Multidisciplinary Scientific Geoconference},
abstract = {The Kuźnica Warężyńska surface reservoir with an area of 5.6 km2 is located in the Silesian district, southern Poland. It was established in 2006 as a result of flooding of a sand pit after over 40 years of mine operation. Currently, it has various functions, the most important of which are flood control and recreational. The long-term dewatering of the pit and its subsequent flooding caused significant changes in the geochemical conditions in the Quaternary aquifer composed of sands and gravels. In addition, numerous buildings around the reservoir do not have a sewage network, which may affect the concentration of such constituents of groundwater as inorganic nitrogen forms, sulphates, bicarbonates or chlorides. In 2018, studies on the chemistry of groundwater from the Quaternary aquifer were carried out around the reservoir. The isotopic composition of nitrates and sulphates in groundwater samples from three selected piezometers was also determined. The results indicate a high diversity of the chemical composition of groundwater around the reservoir. Water electrical conductivity varies in the range 243-1101 μS/cm, nitrate concentrations vary from 0.25 to 57.2 mg/L, bicarbonate – from 24.4 to 396.6 mg/L, Fe2+ from 0 to 3.0 mg/L and Mn2+ from 0.01 to 0.69 mg/L, while sulphate concentrations are more uniform around the reservoir (49-89 mg/L). The results of isotopic studies of S and O in sulphates indicate the origin of sulphates from the oxidation of sulphide minerals and from municipal sewage. Isotopic studies of nitrates suggest their origin from natural fertilizers or municipal sewage. Therefore, it seems that the dominant factor determining the deterioration of groundwater quality is unregulated sewage management around the reservoir. © 2019, International Multidisciplinary Scientific Geoconference. All rights reserved.},
keywords = {},
pubstate = {published},
tppubtype = {proceedings}
}
The Kuźnica Warężyńska surface reservoir with an area of 5.6 km2 is located in the Silesian district, southern Poland. It was established in 2006 as a result of flooding of a sand pit after over 40 years of mine operation. Currently, it has various functions, the most important of which are flood control and recreational. The long-term dewatering of the pit and its subsequent flooding caused significant changes in the geochemical conditions in the Quaternary aquifer composed of sands and gravels. In addition, numerous buildings around the reservoir do not have a sewage network, which may affect the concentration of such constituents of groundwater as inorganic nitrogen forms, sulphates, bicarbonates or chlorides. In 2018, studies on the chemistry of groundwater from the Quaternary aquifer were carried out around the reservoir. The isotopic composition of nitrates and sulphates in groundwater samples from three selected piezometers was also determined. The results indicate a high diversity of the chemical composition of groundwater around the reservoir. Water electrical conductivity varies in the range 243-1101 μS/cm, nitrate concentrations vary from 0.25 to 57.2 mg/L, bicarbonate – from 24.4 to 396.6 mg/L, Fe2+ from 0 to 3.0 mg/L and Mn2+ from 0.01 to 0.69 mg/L, while sulphate concentrations are more uniform around the reservoir (49-89 mg/L). The results of isotopic studies of S and O in sulphates indicate the origin of sulphates from the oxidation of sulphide minerals and from municipal sewage. Isotopic studies of nitrates suggest their origin from natural fertilizers or municipal sewage. Therefore, it seems that the dominant factor determining the deterioration of groundwater quality is unregulated sewage management around the reservoir. © 2019, International Multidisciplinary Scientific Geoconference. All rights reserved.
Ślósarczyk, K.; Jakóbczyk-Karpierz, S.; Rubin, H.; Różkowski, J.; Magiera, T.
International Multidisciplinary Scientific Geoconference, vol. 19, no. 1.2, 2019, ISSN: 13142704.
@proceedings{2-s2.0-85073695832,
title = {Seasonal variation in contamination and sources of polycyclic aromatic hydrocarbons in the cieszyn tufa spring water (Southern poland)},
author = { K. Ślósarczyk and S. Jakóbczyk-Karpierz and H. Rubin and J. Różkowski and T. Magiera},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85073695832&doi=10.5593%2fsgem2019%2f1.2%2fS02.060&partnerID=40&md5=7dd51ab551d5e89a296fa39e1ef10e58},
doi = {10.5593/sgem2019/1.2/S02.060},
issn = {13142704},
year = {2019},
date = {2019-01-01},
journal = {International Multidisciplinary Scientific GeoConference Surveying Geology and Mining Ecology Management, SGEM},
volume = {19},
number = {1.2},
pages = {469-476},
publisher = {International Multidisciplinary Scientific Geoconference},
abstract = {The Cieszyn Tufa Springs is a special area of conservation located in the Western Carpathians (southern Poland). The main subjects of protection are springs that outflow from the contact zone between Cretaceous limestones and slates. Due to a high vulnerability of shallow aquifers within the area of Cieszyn Foothills as well as urbanization and highly-developed industry of the Silesia region, a wide range of contaminants is detected in the spring water. Although microcomponents present in water of the mentioned area are often of geogenic origin, some micro-organic compounds, including polycyclic aromatic hydrocarbons (PAHs), may occur as a result of human activities. In order to quantify PAHs in water from the springs and streams in the area of the Cieszyn Tufa Springs, 4 field campaigns were conducted in summer and autumn of 2017. The concentrations of 16 PAHs were determined using the GC-MS method. The total concentration of examined PAHs observed throughout the considered period ranged between 0.079 and 1.3938 µg/L. The obtained results revealed seasonal variability manifested by the increase in PAHs concentrations in autumn. In a few samples, the sum of the concentrations of 4 PAHs (benzo(b)fluoranthene; benzo(k)fluoranthene; benzo(ghi)perylene and indeno(1;2;3-cd)pyrene) exceeded the drinking water limit (0.1 µg/L). In addition, an attempt has been made to identify the source of target compounds using PAH diagnostic ratios. The comparison of PAHs’ ratios allows to make an assumption that a large proportion of tested compounds derives from car exhausts and low-stack emission and they probably were introduced to spring water through the deposition of air pollutants. © 2019, International Multidisciplinary Scientific Geoconference. All rights reserved.},
keywords = {},
pubstate = {published},
tppubtype = {proceedings}
}
The Cieszyn Tufa Springs is a special area of conservation located in the Western Carpathians (southern Poland). The main subjects of protection are springs that outflow from the contact zone between Cretaceous limestones and slates. Due to a high vulnerability of shallow aquifers within the area of Cieszyn Foothills as well as urbanization and highly-developed industry of the Silesia region, a wide range of contaminants is detected in the spring water. Although microcomponents present in water of the mentioned area are often of geogenic origin, some micro-organic compounds, including polycyclic aromatic hydrocarbons (PAHs), may occur as a result of human activities. In order to quantify PAHs in water from the springs and streams in the area of the Cieszyn Tufa Springs, 4 field campaigns were conducted in summer and autumn of 2017. The concentrations of 16 PAHs were determined using the GC-MS method. The total concentration of examined PAHs observed throughout the considered period ranged between 0.079 and 1.3938 µg/L. The obtained results revealed seasonal variability manifested by the increase in PAHs concentrations in autumn. In a few samples, the sum of the concentrations of 4 PAHs (benzo(b)fluoranthene; benzo(k)fluoranthene; benzo(ghi)perylene and indeno(1;2;3-cd)pyrene) exceeded the drinking water limit (0.1 µg/L). In addition, an attempt has been made to identify the source of target compounds using PAH diagnostic ratios. The comparison of PAHs’ ratios allows to make an assumption that a large proportion of tested compounds derives from car exhausts and low-stack emission and they probably were introduced to spring water through the deposition of air pollutants. © 2019, International Multidisciplinary Scientific Geoconference. All rights reserved.
Ślósarczyk, K.; Jakóbczyk-Karpierz, S.; Rubin, H.; Kowalczyk, A.; Witkowski, A. J.
International Multidisciplinary Scientific Geoconference, vol. 19, no. 1.2, 2019, ISSN: 13142704.
@proceedings{2-s2.0-85073686617,
title = {Isotopic approach to identification of sulphate origin in the triassic aquifer in recharge area of the Łazy bŁĘdowskie well field (Southern poland)},
author = { K. Ślósarczyk and S. Jakóbczyk-Karpierz and H. Rubin and A. Kowalczyk and A.J. Witkowski},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85073686617&doi=10.5593%2fsgem2019%2f1.2%2fS02.046&partnerID=40&md5=b19dc34325f8a6880abe555e5b073702},
doi = {10.5593/sgem2019/1.2/S02.046},
issn = {13142704},
year = {2019},
date = {2019-01-01},
journal = {International Multidisciplinary Scientific GeoConference Surveying Geology and Mining Ecology Management, SGEM},
volume = {19},
number = {1.2},
pages = {361-368},
publisher = {International Multidisciplinary Scientific Geoconference},
abstract = {The Łazy Błędowskie well field located in the area of the Upper Silesia (southern Poland) abstracts water from the Triassic carbonate aquifer. The aquifer is additionally heavily drained by the Zn-Pb ore mines. Due to a deterioration of groundwater quality, caused mainly by sulphate concentration reaching 317 mg/L, most of the wells have been closed and currently only 2 wells are exploited. Sulphates origin in water has been a concern issue of many researchers. However, there are difficulties in identification of sulphates origin in groundwater influenced by severe anthropogenic transformation and negative impacts of various sources of contamination. In order to determine sulphates origin in groundwater, both chemical and isotopic studies were carried out. Analyses of isotopic composition of sulphates (δ34S and δ18 O) were conducted for 5 groundwater samples taken from 3 abstraction wells and 2 observation wells, all of them located within the capture zone to the well field. Additional sample represented sewage from a cocking plant. In addition, archival data on isotopic signature of sulphates in the Triassic aquifer in the study area was used to support the interpretation. The analysis of recent and archival results of isotopic study revealed diversity in sulphates origin in the study area depending on the location of the well, its discharge rate as well as the land use type in the recharge area. The main source of sulphates is oxidation of sulphide minerals present in the Triassic carbonate deposits. Another source of sulphates might be gypsum dissolution that occur locally within the Triassic rocks. In some cases, it was found that a significant proportion of sulphates is of anthropogenic origin: natural and artificial fertilisers, municipal and industrial waste water as well as pollution from atmospheric precipitation. © 2019, International Multidisciplinary Scientific Geoconference. All rights reserved.},
keywords = {},
pubstate = {published},
tppubtype = {proceedings}
}
The Łazy Błędowskie well field located in the area of the Upper Silesia (southern Poland) abstracts water from the Triassic carbonate aquifer. The aquifer is additionally heavily drained by the Zn-Pb ore mines. Due to a deterioration of groundwater quality, caused mainly by sulphate concentration reaching 317 mg/L, most of the wells have been closed and currently only 2 wells are exploited. Sulphates origin in water has been a concern issue of many researchers. However, there are difficulties in identification of sulphates origin in groundwater influenced by severe anthropogenic transformation and negative impacts of various sources of contamination. In order to determine sulphates origin in groundwater, both chemical and isotopic studies were carried out. Analyses of isotopic composition of sulphates (δ34S and δ18 O) were conducted for 5 groundwater samples taken from 3 abstraction wells and 2 observation wells, all of them located within the capture zone to the well field. Additional sample represented sewage from a cocking plant. In addition, archival data on isotopic signature of sulphates in the Triassic aquifer in the study area was used to support the interpretation. The analysis of recent and archival results of isotopic study revealed diversity in sulphates origin in the study area depending on the location of the well, its discharge rate as well as the land use type in the recharge area. The main source of sulphates is oxidation of sulphide minerals present in the Triassic carbonate deposits. Another source of sulphates might be gypsum dissolution that occur locally within the Triassic rocks. In some cases, it was found that a significant proportion of sulphates is of anthropogenic origin: natural and artificial fertilisers, municipal and industrial waste water as well as pollution from atmospheric precipitation. © 2019, International Multidisciplinary Scientific Geoconference. All rights reserved.
Różkowski, J.; Rubin, H.; Rubin, K.; Siwek, P. M.; Ślósarczyk, K.
International Multidisciplinary Scientific Geoconference, vol. 19, no. 1.2, 2019, ISSN: 13142704, (1).
@proceedings{2-s2.0-85073684562,
title = {Chemical composition and water quality of the cieszyn tufa springs (Southern poland). geochemical conditions and anthropogenic hazards},
author = { J. Różkowski and H. Rubin and K. Rubin and P.M. Siwek and K. Ślósarczyk},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85073684562&doi=10.5593%2fsgem2019%2f1.2%2fS02.014&partnerID=40&md5=9874c3a5006afc25654e6eda00b01faa},
doi = {10.5593/sgem2019/1.2/S02.014},
issn = {13142704},
year = {2019},
date = {2019-01-01},
journal = {International Multidisciplinary Scientific GeoConference Surveying Geology and Mining Ecology Management, SGEM},
volume = {19},
number = {1.2},
pages = {105-112},
publisher = {International Multidisciplinary Scientific Geoconference},
abstract = {In 2017, on the order of the Regional Directorate for Environmental Protection in Katowice, the study entitled "Identification of pollution sources affecting the chemical composition of water in the area of Natura 2000 The Cieszyn Tufa Springs PLH240001" was prepared. The unique karst area "The Cieszyn Tufa Springs" is located in the Western Carpathians, in the watershed of the Vistula and the Oder. The studied subslope, descending springs, with the discharge of 0.001-2.5 dm3 /s (2017), drain the first aquifer, associated with the Cieszyn limestones, sandstones, marbled shales of the Carpathian flysch (Cretaceous; Jurassic). Waters from the springs were generally qualified as freshwaters (TDS up to 639 mg/dm3 ), HCO3-Ca and HCO3-SO4-Ca, slightly alkaline (pH 7.08-8.21), medium hard and hard (TH 220-498 mgCaCO3/dm3 ), with the O2 content in water 2.04-8.68 mg/dm3, Eh 78-288 mV. Anthropogenic transformations were manifested by higher TDS values (up to 908 mg/dm3 ), TH (up to 744 mg CaCO3/dm3 ), Cl (up to 150 mg/dm3 ), and the decrease of O2 content in water. The concentrations of the majority of constituents in water corresponded to a good, incidentally poor chemical status, e.g. NO2 concentration up to 2.6 mg/dm3, PO4 up to 4.9 mg/dm3. Disturbing are high concentrations of petroleum compounds in water, among others benzo(a)pyrene (up to 0.045 μg/dm3 ) and PAHs (up to 1.6 μg/dm3 ), corresponding to a poor chemical status. The results of hydrogeochemical modeling showed the increase in the saturation index (SIC) value for calcite from-0.12 (in springs) to 1.22 (in watercourses; the area of intense calcareous tufa precipitation) and a simultaneous reduction of pCO2 (partial pressures of carbon dioxide) from 5488 Pa to 142 Pa. The influence of potential pollution sources (mainly related to agriculture; urbanization and road traffic) on the chemical composition of springs water is favoured by vulnerability of groundwater to pollution. A very high and high degree of vulnerability are dominant, approximate travel time of pollutants to groundwater: <5 years and 5-25 years, respectively. © 2019, International Multidisciplinary Scientific Geoconference. All rights reserved.},
note = {1},
keywords = {},
pubstate = {published},
tppubtype = {proceedings}
}
In 2017, on the order of the Regional Directorate for Environmental Protection in Katowice, the study entitled "Identification of pollution sources affecting the chemical composition of water in the area of Natura 2000 The Cieszyn Tufa Springs PLH240001" was prepared. The unique karst area "The Cieszyn Tufa Springs" is located in the Western Carpathians, in the watershed of the Vistula and the Oder. The studied subslope, descending springs, with the discharge of 0.001-2.5 dm3 /s (2017), drain the first aquifer, associated with the Cieszyn limestones, sandstones, marbled shales of the Carpathian flysch (Cretaceous; Jurassic). Waters from the springs were generally qualified as freshwaters (TDS up to 639 mg/dm3 ), HCO3-Ca and HCO3-SO4-Ca, slightly alkaline (pH 7.08-8.21), medium hard and hard (TH 220-498 mgCaCO3/dm3 ), with the O2 content in water 2.04-8.68 mg/dm3, Eh 78-288 mV. Anthropogenic transformations were manifested by higher TDS values (up to 908 mg/dm3 ), TH (up to 744 mg CaCO3/dm3 ), Cl (up to 150 mg/dm3 ), and the decrease of O2 content in water. The concentrations of the majority of constituents in water corresponded to a good, incidentally poor chemical status, e.g. NO2 concentration up to 2.6 mg/dm3, PO4 up to 4.9 mg/dm3. Disturbing are high concentrations of petroleum compounds in water, among others benzo(a)pyrene (up to 0.045 μg/dm3 ) and PAHs (up to 1.6 μg/dm3 ), corresponding to a poor chemical status. The results of hydrogeochemical modeling showed the increase in the saturation index (SIC) value for calcite from-0.12 (in springs) to 1.22 (in watercourses; the area of intense calcareous tufa precipitation) and a simultaneous reduction of pCO2 (partial pressures of carbon dioxide) from 5488 Pa to 142 Pa. The influence of potential pollution sources (mainly related to agriculture; urbanization and road traffic) on the chemical composition of springs water is favoured by vulnerability of groundwater to pollution. A very high and high degree of vulnerability are dominant, approximate travel time of pollutants to groundwater: <5 years and 5-25 years, respectively. © 2019, International Multidisciplinary Scientific Geoconference. All rights reserved.
2018
Ślósarczyk, K.; Jakóbczyk-Karpierz, S.
In: Przeglad Geologiczny, vol. 66, no. 8, pp. 495-502, 2018, ISSN: 00332151.
@article{2-s2.0-85055270039,
title = {Application of sulfate isotope studies and geochemical modeling in determining processes affecting groundwater chemistry in the Gliwice- Łabedy well-field area [Wykorzystanie modelowania geochemicznego oraz badań izotopowych siarczanów do identyfikacji procesów ksztaltujqcych skład chemiczny wód podziemnych ujecia Gliwice-Łabedy]},
author = { K. Ślósarczyk and S. Jakóbczyk-Karpierz},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85055270039&doi=10.7306%2f2018.3&partnerID=40&md5=3dfca7bfc873a344539e29b5521c1153},
doi = {10.7306/2018.3},
issn = {00332151},
year = {2018},
date = {2018-01-01},
journal = {Przeglad Geologiczny},
volume = {66},
number = {8},
pages = {495-502},
publisher = {Polish Geological Institute},
abstract = {In order to determine geochemical processes affecting chemical composition of groundwater in the Gliwice- Łabedy well-field area two research methods were applied. Chemical analysis allowed us to assess the quality of groundwater in the Triassic karst-fractured-porous aquifer of the southwestern part of the major groundwater basin no. 330. The chemical composition of groundwater is distinguished by spatial heterogeneity highlighted by higher mineralization and concentrations of individual ions in the western area. In addition, all samples collected in 2016 were analyzed for the δ35S and δ18O to identify sources of sulfates in the waters examined. The study revealed a different origin of these ions depending on location of the wells sampled. The results of chemical analysis and archival data allowed for application of geochemical modeling in identification of processes taking part in groundwater chemistry evolution. Simulations of processes controlling water chemistry within the Triassic aquifer were conducted using The Geochemist's Workbench 10.0.6. The examined processes encompassed dissolution of minerals forming the carbonate aquifer and Miocene evaporates overlying the Triassic aquifer as well as mixing of groundwater and surface water. © 2018 Polish Geological Institute. All rights reserved.},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
In order to determine geochemical processes affecting chemical composition of groundwater in the Gliwice- Łabedy well-field area two research methods were applied. Chemical analysis allowed us to assess the quality of groundwater in the Triassic karst-fractured-porous aquifer of the southwestern part of the major groundwater basin no. 330. The chemical composition of groundwater is distinguished by spatial heterogeneity highlighted by higher mineralization and concentrations of individual ions in the western area. In addition, all samples collected in 2016 were analyzed for the δ35S and δ18O to identify sources of sulfates in the waters examined. The study revealed a different origin of these ions depending on location of the wells sampled. The results of chemical analysis and archival data allowed for application of geochemical modeling in identification of processes taking part in groundwater chemistry evolution. Simulations of processes controlling water chemistry within the Triassic aquifer were conducted using The Geochemist's Workbench 10.0.6. The examined processes encompassed dissolution of minerals forming the carbonate aquifer and Miocene evaporates overlying the Triassic aquifer as well as mixing of groundwater and surface water. © 2018 Polish Geological Institute. All rights reserved.
Sołtysiak, M.; Dąbrowska, D.; Ślósarczyk, K.
International Multidisciplinary Scientific Geoconference, vol. 18, no. 5.4, 2018, ISSN: 13142704, (2).
@proceedings{2-s2.0-85058872246,
title = {Natural and formal-legal aspect of the environmental impact assessment of the planned reclamation of mining damage in the szotkowka valley (Southern poland)},
author = { M. Sołtysiak and D. Dąbrowska and K. Ślósarczyk},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85058872246&doi=10.5593%2fsgem2018%2f5.4%2fS23.064&partnerID=40&md5=6780843f0a53ff52e95bd3870c99839e},
doi = {10.5593/sgem2018/5.4/S23.064},
issn = {13142704},
year = {2018},
date = {2018-01-01},
journal = {International Multidisciplinary Scientific GeoConference Surveying Geology and Mining Ecology Management, SGEM},
volume = {18},
number = {5.4},
pages = {501-508},
publisher = {International Multidisciplinary Scientific Geoconference},
abstract = {Underground mining exploitation in the Upper Silesian Coal Basin results in lowering of a land surface. It has its environmental consequences. These processes favor the creation of wetlands and floodplains, which often help to increase biodiversity. However, progressive lowering of the land surface disrupts flow of rivers, force change of land use, and may lead to real risks for building facilities. Therefore, it is necessary to undertake reclamation works, which consist in filling depression area. All this leads to many environmental problems. The article deals with the problem of liquidation of mining damages, by using post-mining waste. It is based on a case study of a 1.5-kilometer stretch of the Szotkowka valley in Polomia (southern Poland), where the site was lowered and a still-developing floodplain of 21 ha has been created. According to the project, reclamation project will cover liquidation of the floodplain and reconstruction of the riverbed. Work performance will require the deposit of 2.2 million m3 of aggregate in the basin. The use of coal mine waste is planned. Static leaching tests carried out for Environmental Impact Assessment were the basis for recognizing that the material coming from the mines would not pose a threat to the soil and water environment. However, it was omitted that the obtained pollution leaching results were referred to the laboratory sample (90-100 g) only, not to 2.2 million m3 of post – mining waste. The authors reinterpreted the results of the leaching tests, basing on the European standard EN 12457-4 [1]. They obtained results in mg/kg of a dry matter, and then they calculated the potential mass pollution which can be leached from the entire volume of the material which is planned to be used in engineering works. They also took into account the results of the monitoring of underground waters of the mining waste landfill "Pochwacie", which is situated opposite to the planned works, on the left bank of the Szotkowka River. The obtained results confirmed, that the negative impact of planned reclamation works on the soil and water environment will be significant. As a consequence, a new source of pollution of underground and surface waters will be created. This aspect has been completely neglected in the environmental impact assessment procedure. As part of the article, the authors also presented formal and legal conditions for using mining waste in the reclamation of the areas of mining damage. The results of the presented analyses made it possible to indicate several guidelines as the authors’ proposal, and to introduce them into legal solutions in the scope of using post-mining waste for engineering works. © 2018, International Multidisciplinary Scientific Geoconference. All rights reserved.},
note = {2},
keywords = {},
pubstate = {published},
tppubtype = {proceedings}
}
Underground mining exploitation in the Upper Silesian Coal Basin results in lowering of a land surface. It has its environmental consequences. These processes favor the creation of wetlands and floodplains, which often help to increase biodiversity. However, progressive lowering of the land surface disrupts flow of rivers, force change of land use, and may lead to real risks for building facilities. Therefore, it is necessary to undertake reclamation works, which consist in filling depression area. All this leads to many environmental problems. The article deals with the problem of liquidation of mining damages, by using post-mining waste. It is based on a case study of a 1.5-kilometer stretch of the Szotkowka valley in Polomia (southern Poland), where the site was lowered and a still-developing floodplain of 21 ha has been created. According to the project, reclamation project will cover liquidation of the floodplain and reconstruction of the riverbed. Work performance will require the deposit of 2.2 million m3 of aggregate in the basin. The use of coal mine waste is planned. Static leaching tests carried out for Environmental Impact Assessment were the basis for recognizing that the material coming from the mines would not pose a threat to the soil and water environment. However, it was omitted that the obtained pollution leaching results were referred to the laboratory sample (90-100 g) only, not to 2.2 million m3 of post – mining waste. The authors reinterpreted the results of the leaching tests, basing on the European standard EN 12457-4 [1]. They obtained results in mg/kg of a dry matter, and then they calculated the potential mass pollution which can be leached from the entire volume of the material which is planned to be used in engineering works. They also took into account the results of the monitoring of underground waters of the mining waste landfill "Pochwacie", which is situated opposite to the planned works, on the left bank of the Szotkowka River. The obtained results confirmed, that the negative impact of planned reclamation works on the soil and water environment will be significant. As a consequence, a new source of pollution of underground and surface waters will be created. This aspect has been completely neglected in the environmental impact assessment procedure. As part of the article, the authors also presented formal and legal conditions for using mining waste in the reclamation of the areas of mining damage. The results of the presented analyses made it possible to indicate several guidelines as the authors’ proposal, and to introduce them into legal solutions in the scope of using post-mining waste for engineering works. © 2018, International Multidisciplinary Scientific Geoconference. All rights reserved.